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  7. Borane-tetrahydrofuran complex, 1M soln. in THF, stab. with 5mmol NaBH4, Thermo Scientific™

Borane-tetrahydrofuran complex, 1M soln. in THF, stab. with 5mmol NaBH4, Thermo Scientific™

Produktkod. 11486800
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Produktkod. 11486800 Leverantör Thermo Scientific Alfa Aesar Leverantörsnummer L13961.AC
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Beskrivning

This Thermo Scientific brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific.

Applications
Borane-tetrahydrofuran complex is an important reagent used in the reduction of certain functional groups viz. aldehyde, ketone, carboxylic acid, amide, oxime, imine and nitrile. It is also used as hydro borating agent. It acts as a borane source for oxazaborolidine catalyzed asymmetric reductions. It is utilized to reduce nylon surface amide groups to secondary amines.

Solubility
Miscible and reacts violently with water.

Notes
Air and moisture sensitive. Forms explosive peroxides in contact with air. Incompatible with acids, acid chlorides, acid anhydrides, oxidizing agents and alcohols. On hydrolysis, it forms hydrogen and boric acid.
TRUSTED_SUSTAINABILITY

Kemiska identifierare

CAS 14044-65-6
Molekylformel C4H11BO
Molekylvikt (g/mol) 85.94
MDL-nummer MFCD00012429
InChI-nyckel RMCYTHFAWCWRFA-UHFFFAOYSA-N
Synonym borane-tetrahydrofuran complex, tetrahydrofuran borane, bh3.thf, borane tetrahydrofuran complex solution, borane-d3-thf complex solution, borane-tetrahydrofuran, unii-5ear4err1l, oxolane borane, boron; oxolane, borane thf
PubChem CID 11062302
IUPAC-namn boron;oxolane
LEDER B.C1CCOC1

Specifikationer

Kemiskt namn eller material Borane-tetrahydrofuran complex
Namnnotering stabilized with 5mmol NaBH4
Densitet 0.878
Flampunkt −21°C (−8°F)
Linjär formel BH3/(CH2)4O
Kvantitet 25 mL
UN-nummer UN3148
Beilstein 3668402
Känslighet Air and moisture sensitive
Löslighetsinformation Miscible and reacts violently with water.
Formel vikt 85.94
Koncentration eller sammansättning (efter analyt eller komponenter) 1M soln. in THF
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