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(Trimethylsilyl)diazomethane, 2M in hexanes

Produktkod. 11322739
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Produktkod. 11322739 Leverantör Thermo Scientific Alfa Aesar Leverantörsnummer H26744.AA
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Beskrivning

CAS: 18107-18-1 | C4H10N2Si | 114.223 g/mol

(Trimethylsilyl)diazomethane is used as a methylating agent in organic chemistry. It is utilized in Gas Chromatography- Mass-Spectrometry (GC-MS) for the analysis of various carboxylic compounds. It is involved as a reagent in the Doyle-Kirmse reaction with allyl sulfides and allyl amines. It is considered and used as a less-explosive replacement fordiazomethane. It is also used as a reactant for Unnatural alfa-amino acid derivatives containing gem-bisphosphonates through Michael addition reaction, imidazolo[2,1-b]benzothiazole derivatives and aigialomycin D analogues.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(Trimethylsilyl)diazomethane is used as a methylating agent in organic chemistry. It is utilized in Gas Chromatography- Mass-Spectrometry (GC-MS) for the analysis of various carboxylic compounds. It is involved as a reagent in the Doyle-Kirmse reaction with allyl sulfides and allyl amines. It is considered and used as a less-explosive replacement fordiazomethane. It is also used as a reactant for Unnatural alfa-amino acid derivatives containing gem-bisphosphonates through Michael addition reaction, imidazolo[2,1-b]benzothiazole derivatives and aigialomycin D analogues.

Solubility
Immiscible with water. Miscible with organic solvents.

Notes
(Trimethylsilyl)diazomethane (TMSD) in alcoholic solvents under acidic or basic conditions can lead to the formation of diazomethane. TMSD is under review by the National Toxicological Program for potential inhalation hazards.Incompatible with oxidizing agents, chlorine, fluorine and perchlorates.
TRUSTED_SUSTAINABILITY

Kemiska identifierare

CAS 18107-18-1
Molekylformel C4H10N2Si
Molekylvikt (g/mol) 114.223
MDL-nummer MFCD00053946
InChI-nyckel ONDSBJMLAHVLMI-UHFFFAOYSA-N
Synonym trimethylsilyl diazomethane, trimethylsilyldiazomethane, diazomethyl trimethylsilane, tms-diazomethane, diazomethyl trimethyl silane, tmschn2, silane, diazomethyl trimethyl, unii-qi98hqo8c4, diazomethyl-trimethyl-silane, qi98hqo8c4
PubChem CID 167693
IUPAC-namn diazomethyl(trimethyl)silane
LEDER C[Si](C)(C)C=[N+]=[N-]

Specifikationer

Kemiskt namn eller material (Trimethylsilyl)diazomethane
Kvantitet 5 mL
UN-nummer UN3383
Beilstein 1902903
Flampunkt −23°C (−10°F)
Löslighetsinformation Immiscible with water. Miscible with organic solvents.
Formel vikt 114.22
Koncentration eller sammansättning (efter analyt eller komponenter) 2M in hexanes
Känslighet Light and moisture sensitive
Densitet 0.718

RUO – Research Use Only

Produkttitel
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