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  7. Zirconium(IV) chloride, 98%, cont. 1-2% hafnium(IV) chloride, Thermo Scientific Chemicals

Zirconium(IV) chloride, 98%, cont. 1-2% hafnium(IV) chloride, Thermo Scientific Chemicals

Produktkod. 11373716
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Produktkod. 11373716 Leverantör Thermo Scientific Alfa Aesar Leverantörsnummer L14891.18
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Beskrivning

Zirconium(IV) chloride catalyzes the trans-hydrostannylation of acetylenes with Tri-n-butyl­tin hydride. It is used as a superior catalyst for the fries rearrangement of aryl acetates, giving the least hindered ortho-acetyl phenol in high yields at ambient temperatures. In the presence of ZrCl4, chloromethyl ethers are formed under mild conditions from acid chlorides and trioxane or paraformaldehyde.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Zirconium(IV) chloride catalyzes the trans-hydrostannylation of acetylenes with Tri-n-butyl­tin hydride. It is used as a superior catalyst for the fries rearrangement of aryl acetates, giving the least hindered ortho-acetyl phenol in high yields at ambient temperatures. In the presence of ZrCl4, chloromethyl ethers are formed under mild conditions from acid chlorides and trioxane or paraformaldehyde.

Solubility
Reacts with water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Handle and store under inert gas. It is sensitive to moisture. Incompatible with bases and oxidizing agents.
TRUSTED_SUSTAINABILITY

Kemiska identifierare

CAS 10026-11-6
Molekylformel ZrCl4
MDL-nummer MFCD00011306
Synonym Zirconium tetrachloride

Specifikationer

Kemiskt namn eller material Zirconium(IV) chloride
Smältpunkt 331°C (sublimation)
Kvantitet 50 g
Anteckningar om analysprocent cont. 1 to 2% hafnium(IV) chloride
UN-nummer UN2503
Merck Index 14,10174
Löslighetsinformation Reacts with water.
Formel vikt 233.03
Procent renhet 98%
Känslighet Moisture sensitive
Densitet 2.803
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RUO – Research Use Only

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