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Fenylfosfiner och derivat

Organofosforföreningar som består av en fenylgrupp med en fosfingruppssubstitution i följande struktur: C6H5PH2; fospingrupper har en fosforatom bunden till tre väteatomer. De är fosforanalogen av anilin.

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1

Trifenylfosfinoxid, 99 %, Thermo Scientific Chemicals

CAS: 791-28-6 Molekylformel: C18H15OP Molekylvikt (g/mol): 278.29 MDL-nummer: MFCD00002080 MFCD03458802 InChI-nyckel: FIQMHBFVRAXMOP-UHFFFAOYSA-N Synonym: triphenylphosphine oxide,phosphine oxide, triphenyl,triphenyl phosphorus oxide,triphenyl phosphine oxide,triphenylphosphane oxide,tppo,triphenylphosphineoxide,ph3po,diphenylphosphoroso benzene,triphenylphosphanoxid PubChem CID: 13097 ChEBI: CHEBI:36601 IUPAC-namn: difenylfosforylbensen LEDER: O=P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1

EDGE
Molekylformel C18H15OP
PubChem CID 13097
MDL-nummer MFCD00002080 MFCD03458802
IUPAC-namn difenylfosforylbensen
CAS 791-28-6
InChI-nyckel FIQMHBFVRAXMOP-UHFFFAOYSA-N
LEDER O=P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
ChEBI CHEBI:36601
Molekylvikt (g/mol) 278.29
Synonym triphenylphosphine oxide,phosphine oxide, triphenyl,triphenyl phosphorus oxide,triphenyl phosphine oxide,triphenylphosphane oxide,tppo,triphenylphosphineoxide,ph3po,diphenylphosphoroso benzene,triphenylphosphanoxid
2

(Ethoxycarbonylmethylene)triphenylphosphorane, 98+%

CAS: 1099-45-2 Molekylformel: C22H21O2P Molekylvikt (g/mol): 348.38 MDL-nummer: MFCD00009183 InChI-nyckel: IIHPVYJPDKJYOU-UHFFFAOYSA-N Synonym: carbethoxymethylene triphenylphosphorane,ethyl triphenylphosphoranylidene acetate,triphenylcarbethoxymethylenephosphorane,acetic acid, triphenylphosphoranylidene-, ethyl ester,ethyl 2-triphenylphosphoranylidene acetate,ethoxycarbonylmethylene triphenylphosphorane,carboethoxymethylidenetriphenylphosphorane,ethyl triphenylphosphoranilidene acetate,carbethoxytriphenylphosphonium methylide,carbethoxymethylidenetriphenylphosphorane PubChem CID: 70670 IUPAC-namn: etyl-2-(trifenyl-$l^{5}-fosfanyliden)acetat LEDER: CCOC(=O)C=P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1

Molekylformel C22H21O2P
PubChem CID 70670
MDL-nummer MFCD00009183
IUPAC-namn etyl-2-(trifenyl-$l^{5}-fosfanyliden)acetat
CAS 1099-45-2
InChI-nyckel IIHPVYJPDKJYOU-UHFFFAOYSA-N
LEDER CCOC(=O)C=P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
Molekylvikt (g/mol) 348.38
Synonym carbethoxymethylene triphenylphosphorane,ethyl triphenylphosphoranylidene acetate,triphenylcarbethoxymethylenephosphorane,acetic acid, triphenylphosphoranylidene-, ethyl ester,ethyl 2-triphenylphosphoranylidene acetate,ethoxycarbonylmethylene triphenylphosphorane,carboethoxymethylidenetriphenylphosphorane,ethyl triphenylphosphoranilidene acetate,carbethoxytriphenylphosphonium methylide,carbethoxymethylidenetriphenylphosphorane
3

Dichlorobis(tri-o-tolylphosphine)palladium(II), 95%

CAS: 40691-33-6 Molekylformel: C42H42Cl2P2Pd Molekylvikt (g/mol): 786.06 MDL-nummer: MFCD00274659 InChI-nyckel: GMLMZLGOMMIIMA-UHFFFAOYSA-L Synonym: palladium,dichlorobis tris 2-methylphenyl phosphine PubChem CID: 90656943 IUPAC-namn: palladium;tris(2-metylfenyl)fosfan;diklorid LEDER: Cl[Pd++]Cl.CC1=CC=CC=C1P(C1=C(C)C=CC=C1)C1=C(C)C=CC=C1.CC1=CC=CC=C1P(C1=C(C)C=CC=C1)C1=C(C)C=CC=C1

Molekylformel C42H42Cl2P2Pd
PubChem CID 90656943
MDL-nummer MFCD00274659
IUPAC-namn palladium;tris(2-metylfenyl)fosfan;diklorid
CAS 40691-33-6
InChI-nyckel GMLMZLGOMMIIMA-UHFFFAOYSA-L
LEDER Cl[Pd++]Cl.CC1=CC=CC=C1P(C1=C(C)C=CC=C1)C1=C(C)C=CC=C1.CC1=CC=CC=C1P(C1=C(C)C=CC=C1)C1=C(C)C=CC=C1
Molekylvikt (g/mol) 786.06
Synonym palladium,dichlorobis tris 2-methylphenyl phosphine
4

4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene, 97%

CAS: 161265-03-8 Molekylformel: C39H32OP2 Molekylvikt (g/mol): 578.63 MDL-nummer: MFCD00233866 InChI-nyckel: CXNIUSPIQKWYAI-UHFFFAOYSA-N Synonym: xantphos,4,5-bis diphenylphosphino-9,9-dimethylxanthene,9,9-dimethyl-4,5-bis diphenylphosphino xanthene,9,9-dimethyl-9h-xanthene-4,5-diyl bis diphenylphosphine,dimethylbisdiphenylphosphinoxanthene,unii-nmu72mog9b,nmu72mog9b,9,9-dimethyl-9h-xanthene-4,5-diyl bis diphenylphosphane,5-diphenylphosphanyl-9,9-dimethylxanthen-4-yl-diphenylphosphane,4,5-bis-diphenylphosphanyl-9,9-dimethyl-9h-xanthene PubChem CID: 636044 IUPAC-namn: (5-difenylfosfanyl-9,9-dimetylxanten-4-yl)-difenylfosfan LEDER: CC1(C)C2=C(OC3=C1C=CC=C3P(C1=CC=CC=C1)C1=CC=CC=C1)C(=CC=C2)P(C1=CC=CC=C1)C1=CC=CC=C1

Molekylformel C39H32OP2
PubChem CID 636044
MDL-nummer MFCD00233866
IUPAC-namn (5-difenylfosfanyl-9,9-dimetylxanten-4-yl)-difenylfosfan
CAS 161265-03-8
InChI-nyckel CXNIUSPIQKWYAI-UHFFFAOYSA-N
LEDER CC1(C)C2=C(OC3=C1C=CC=C3P(C1=CC=CC=C1)C1=CC=CC=C1)C(=CC=C2)P(C1=CC=CC=C1)C1=CC=CC=C1
Molekylvikt (g/mol) 578.63
Synonym xantphos,4,5-bis diphenylphosphino-9,9-dimethylxanthene,9,9-dimethyl-4,5-bis diphenylphosphino xanthene,9,9-dimethyl-9h-xanthene-4,5-diyl bis diphenylphosphine,dimethylbisdiphenylphosphinoxanthene,unii-nmu72mog9b,nmu72mog9b,9,9-dimethyl-9h-xanthene-4,5-diyl bis diphenylphosphane,5-diphenylphosphanyl-9,9-dimethylxanthen-4-yl-diphenylphosphane,4,5-bis-diphenylphosphanyl-9,9-dimethyl-9h-xanthene
5

Chlorotris(triphenylphosphine)rhodium(I), 97%

CAS: 14694-95-2 Molekylformel: C54H45ClP3Rh Molekylvikt (g/mol): 925.23 MDL-nummer: MFCD00010016 InChI-nyckel: IXAYKDDZKIZSPV-UHFFFAOYSA-M Synonym: chlorotris triphenylphosphine rhodium i,chlorotris triphenylphosphine rhodium,tris triphenylphosphine rhodium i chloride,tris triphenylphosphine chlororhodium,wilkinson's catalyst,unii-0fv534bkev,tris triphenylphosphine rhodium chloride,0fv534bkev,rhodium; triphenylphosphane; chloride PubChem CID: 84599 IUPAC-namn: rodium;trifenylfosfan;klorid LEDER: [Cl-].[Rh+].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1

Molekylformel C54H45ClP3Rh
PubChem CID 84599
MDL-nummer MFCD00010016
IUPAC-namn rodium;trifenylfosfan;klorid
CAS 14694-95-2
InChI-nyckel IXAYKDDZKIZSPV-UHFFFAOYSA-M
LEDER [Cl-].[Rh+].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1
Molekylvikt (g/mol) 925.23
Synonym chlorotris triphenylphosphine rhodium i,chlorotris triphenylphosphine rhodium,tris triphenylphosphine rhodium i chloride,tris triphenylphosphine chlororhodium,wilkinson's catalyst,unii-0fv534bkev,tris triphenylphosphine rhodium chloride,0fv534bkev,rhodium; triphenylphosphane; chloride
7

3-Methyl-1-phenyl-2-phospholene 1-oxide, 94%

CAS: 707-61-9 Molekylformel: C11H13OP Molekylvikt (g/mol): 192.198 MDL-nummer: MFCD00014518 InChI-nyckel: YMKWWHFRGALXLE-UHFFFAOYSA-N Synonym: 3-methyl-1-phenyl-2-phospholene 1-oxide,3-methyl-1-phenyl-2-phospholene-1-oxide,2,3-dihydro-4-methyl-1-phenyl-1h-phosphole 1-oxide,1h-phosphole, 2,3-dihydro-4-methyl-1-phenyl-, 1-oxide,4-methyl-1-phenyl-2,3-dihydro-1h-phosphole 1-oxide,2-phospholene, 3-methyl-1-phenyl-, 1-oxide,2,3-dihydro-4-methyl-1-phenyl-1h-phosphole, 1-oxide,4-methyl-1-phenyl-2,3-dihydro-1$l^ 5-phosphole 1-oxide,3-methyl-1-phenyl-4,5-dihydro-1??-phosphol-1-one,2-phospholene, 1-oxide PubChem CID: 69722 IUPAC-namn: 4-metyl-1-fenyl-2,3-dihydro-1$l^{5}-fosfol-1-oxid LEDER: CC1=CP(=O)(CC1)C2=CC=CC=C2

Molekylformel C11H13OP
PubChem CID 69722
MDL-nummer MFCD00014518
IUPAC-namn 4-metyl-1-fenyl-2,3-dihydro-1$l^{5}-fosfol-1-oxid
CAS 707-61-9
InChI-nyckel YMKWWHFRGALXLE-UHFFFAOYSA-N
LEDER CC1=CP(=O)(CC1)C2=CC=CC=C2
Molekylvikt (g/mol) 192.198
Synonym 3-methyl-1-phenyl-2-phospholene 1-oxide,3-methyl-1-phenyl-2-phospholene-1-oxide,2,3-dihydro-4-methyl-1-phenyl-1h-phosphole 1-oxide,1h-phosphole, 2,3-dihydro-4-methyl-1-phenyl-, 1-oxide,4-methyl-1-phenyl-2,3-dihydro-1h-phosphole 1-oxide,2-phospholene, 3-methyl-1-phenyl-, 1-oxide,2,3-dihydro-4-methyl-1-phenyl-1h-phosphole, 1-oxide,4-methyl-1-phenyl-2,3-dihydro-1$l^ 5-phosphole 1-oxide,3-methyl-1-phenyl-4,5-dihydro-1??-phosphol-1-one,2-phospholene, 1-oxide
9

n-Propyltriphenylphosphonium bromide, 99%, Thermo Scientific™

CAS: 15912-75-1 Molekylformel: C21H22P Molekylvikt (g/mol): 305.38 MDL-nummer: MFCD00011843 InChI-nyckel: MSXNDXIAUQJHNS-UHFFFAOYSA-N Synonym: propyl triphenyl phosphonium bromide,propyltriphenylphosphonium bromide,triphenylpropylphosphonium bromide at PubChem CID: 88526383 IUPAC-namn: triphenyl(propyl)phosphanium;hydrobromide LEDER: CCC[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1

Molekylformel C21H22P
PubChem CID 88526383
MDL-nummer MFCD00011843
IUPAC-namn triphenyl(propyl)phosphanium;hydrobromide
CAS 15912-75-1
InChI-nyckel MSXNDXIAUQJHNS-UHFFFAOYSA-N
LEDER CCC[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
Molekylvikt (g/mol) 305.38
Synonym propyl triphenyl phosphonium bromide,propyltriphenylphosphonium bromide,triphenylpropylphosphonium bromide at