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Organofosforföreningar

Organiska föreningar som innehåller en eller flera fosforatomer.
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1 – 15 av 89 Resultat
1

Tetrametylfosfoniumbromid, 97 %, Thermo Scientific Chemicals

CAS: 4519-28-2 Molekylformel: C4H12BrP Molekylvikt (g/mol): 171.02 MDL-nummer: MFCD00011802 InChI-nyckel: ZTXFOCMYRCGSMU-UHFFFAOYSA-M Synonym: tetramethylphosphonium bromide,tetramethylphosphanium bromide,acmc-1ai8x,ch3 4pbr,tetramethyl phosphonium bromide,phosphonium, tetramethyl-, bromide PubChem CID: 357594 IUPAC-namn: tetrametylfosfanium;bromid LEDER: [Br-].C[P+](C)(C)C

EDGE
Molekylformel C4H12BrP
PubChem CID 357594
MDL-nummer MFCD00011802
IUPAC-namn tetrametylfosfanium;bromid
CAS 4519-28-2
InChI-nyckel ZTXFOCMYRCGSMU-UHFFFAOYSA-M
LEDER [Br-].C[P+](C)(C)C
Molekylvikt (g/mol) 171.02
Synonym tetramethylphosphonium bromide,tetramethylphosphanium bromide,acmc-1ai8x,ch3 4pbr,tetramethyl phosphonium bromide,phosphonium, tetramethyl-, bromide
2

Thermo Scientific Chemicals Lawessons reagens, 97 %

CAS: 19172-47-5 Molekylformel: C14H14O2P2S4 Molekylvikt (g/mol): 404.452 MDL-nummer: MFCD00005171 InChI-nyckel: CFHGBZLNZZVTAY-UHFFFAOYSA-N Synonym: lawesson's reagent,lawesson reagent,2,4-bis 4-methoxyphenyl-1,3,2,4-dithiadiphosphetane 2,4-disulfide,unii-a4125mq8rx,1,3,2,4-dithiadiphosphetane, 2,4-bis 4-methoxyphenyl-, 2,4-disulfide,2,4-bis 4-methoxyphenyl-2,4-dithioxo-1,3,2,4-dithiadiphosphetane,2,4-bis 4-methoxyphenyl-1,3,2,4-dithiadiphosphetane-2,4-disulfide,2,4-bis 4-methoxyphenyl-1,3-dithia-2,4-diphosphetane 2,4-disulfide,2,4-bis 4-methoxyphenyl-1,3-dithia-2,4-diphosphetane 2,4-disulphide,4-methoxyphenylthiophosphoric cyclic di thioanhydride PubChem CID: 87949 IUPAC-namn: 2,4-bis(4-metoxifenyl)-2,4-bis(sulfanyliden)-1,3,2$l^{5},4$l^{5}-ditiadifosfetan LEDER: COC1=CC=C(C=C1)P2(=S)SP(=S)(S2)C3=CC=C(C=C3)OC

Molekylformel C14H14O2P2S4
PubChem CID 87949
MDL-nummer MFCD00005171
IUPAC-namn 2,4-bis(4-metoxifenyl)-2,4-bis(sulfanyliden)-1,3,2$l^{5},4$l^{5}-ditiadifosfetan
CAS 19172-47-5
InChI-nyckel CFHGBZLNZZVTAY-UHFFFAOYSA-N
LEDER COC1=CC=C(C=C1)P2(=S)SP(=S)(S2)C3=CC=C(C=C3)OC
Molekylvikt (g/mol) 404.452
Synonym lawesson's reagent,lawesson reagent,2,4-bis 4-methoxyphenyl-1,3,2,4-dithiadiphosphetane 2,4-disulfide,unii-a4125mq8rx,1,3,2,4-dithiadiphosphetane, 2,4-bis 4-methoxyphenyl-, 2,4-disulfide,2,4-bis 4-methoxyphenyl-2,4-dithioxo-1,3,2,4-dithiadiphosphetane,2,4-bis 4-methoxyphenyl-1,3,2,4-dithiadiphosphetane-2,4-disulfide,2,4-bis 4-methoxyphenyl-1,3-dithia-2,4-diphosphetane 2,4-disulfide,2,4-bis 4-methoxyphenyl-1,3-dithia-2,4-diphosphetane 2,4-disulphide,4-methoxyphenylthiophosphoric cyclic di thioanhydride
3

Di-^m-bromobis(tri-tert-butylphosphine)dipalladium(I)

CAS: 185812-86-6 Molekylformel: C24H56Br2P2Pd2 Molekylvikt (g/mol): 779.31 MDL-nummer: MFCD04114019 InChI-nyckel: JWWUTWDBVLEWDQ-UHFFFAOYSA-P Synonym: palladium i tri-tert-butylphosphine bromide,acmc-1c5o0,qmkdjymohbicon-uhfffaoysa-m,palladium i tri-tertbutylphosphine bromide PubChem CID: 71317307 IUPAC-namn: bis(tri-tert-butyl-λ5-fosfanyl)cyklodipalladabroman LEDER: CC(C)(C)P([Pd]1[Br][Pd]([Br]1)P(C(C)(C)C)(C(C)(C)C)C(C)(C)C)(C(C)(C)C)C(C)(C)C

Molekylformel C24H56Br2P2Pd2
PubChem CID 71317307
MDL-nummer MFCD04114019
IUPAC-namn bis(tri-tert-butyl-λ5-fosfanyl)cyklodipalladabroman
CAS 185812-86-6
InChI-nyckel JWWUTWDBVLEWDQ-UHFFFAOYSA-P
LEDER CC(C)(C)P([Pd]1[Br][Pd]([Br]1)P(C(C)(C)C)(C(C)(C)C)C(C)(C)C)(C(C)(C)C)C(C)(C)C
Molekylvikt (g/mol) 779.31
Synonym palladium i tri-tert-butylphosphine bromide,acmc-1c5o0,qmkdjymohbicon-uhfffaoysa-m,palladium i tri-tertbutylphosphine bromide
4

Tri-n-butylphosphine, 94%

CAS: 998-40-3 Molekylformel: C12H27P Molekylvikt (g/mol): 202.32 MDL-nummer: MFCD00009462 InChI-nyckel: TUQOTMZNTHZOKS-UHFFFAOYSA-N Synonym: tributylphosphine,tri-n-butylphosphine,phosphine, tributyl,tris butyl phosphine,tributylfosfin,tributylfosfin czech,tributyl-phosphane,unii-0o52fjr7wn,tri-n-butyl phosphine,tributyl phosphine tbp PubChem CID: 13831 IUPAC-namn: tributylfosfan LEDER: CCCCP(CCCC)CCCC

Molekylformel C12H27P
PubChem CID 13831
MDL-nummer MFCD00009462
IUPAC-namn tributylfosfan
CAS 998-40-3
InChI-nyckel TUQOTMZNTHZOKS-UHFFFAOYSA-N
LEDER CCCCP(CCCC)CCCC
Molekylvikt (g/mol) 202.32
Synonym tributylphosphine,tri-n-butylphosphine,phosphine, tributyl,tris butyl phosphine,tributylfosfin,tributylfosfin czech,tributyl-phosphane,unii-0o52fjr7wn,tri-n-butyl phosphine,tributyl phosphine tbp
5

(2R,3R)-(+)-Bis(diphenylphosphino)butane, 98%

CAS: 74839-84-2 Molekylformel: C28H28P2 Molekylvikt (g/mol): 426.48 MDL-nummer: MFCD00075403 InChI-nyckel: FWXAUDSWDBGCMN-ZBXWWWQKNA-N Synonym: r,r-chiraphos,chiraphos, r,r,unii-1t086b9q1j,2r,3r-+-bis diphenylphosphino butane,2r,3r-butane-2,3-diylbis diphenylphosphine,2r,3r-+-2,3-bis diphenylphosphino butane,cira,phosphine, 1r,2r-1,2-dimethyl-1,2-ethanediyl bis diphenyl,2r,3r-bis diphenylphosphino butane,r,?r ?-?chiraphos PubChem CID: 2724948 IUPAC-namn: [(2R,3R)-3-difenylfosfanylbutan-2-yl]-difenylfosfan LEDER: C[C@H]([C@@H](C)P(C1=CC=CC=C1)C1=CC=CC=C1)P(C1=CC=CC=C1)C1=CC=CC=C1

Molekylformel C28H28P2
PubChem CID 2724948
MDL-nummer MFCD00075403
IUPAC-namn [(2R,3R)-3-difenylfosfanylbutan-2-yl]-difenylfosfan
CAS 74839-84-2
InChI-nyckel FWXAUDSWDBGCMN-ZBXWWWQKNA-N
LEDER C[C@H]([C@@H](C)P(C1=CC=CC=C1)C1=CC=CC=C1)P(C1=CC=CC=C1)C1=CC=CC=C1
Molekylvikt (g/mol) 426.48
Synonym r,r-chiraphos,chiraphos, r,r,unii-1t086b9q1j,2r,3r-+-bis diphenylphosphino butane,2r,3r-butane-2,3-diylbis diphenylphosphine,2r,3r-+-2,3-bis diphenylphosphino butane,cira,phosphine, 1r,2r-1,2-dimethyl-1,2-ethanediyl bis diphenyl,2r,3r-bis diphenylphosphino butane,r,?r ?-?chiraphos
6

Bis(tri-tert-butylphosphine)palladium(0)

CAS: 53199-31-8 Molekylformel: C24H54P2Pd Molekylvikt (g/mol): 511.06 MDL-nummer: MFCD03094580 InChI-nyckel: MXQOYLRVSVOCQT-UHFFFAOYSA-N Synonym: bis tri-tert-butylphosphine palladium 0,bis tri-t-butylphosphine palladium 0,bis tri-tert-butylphosphine palladium,bis tri-tert-butylphosphane palladium,palladium; tritert-butylphosphane,palladium, bis tris 1,1-dimethylethyl phosphine,pd p tbu 3 2,pd t-bu3p 2,bis tri-t-butylphosphine palladium,di tri-tert-butylphosphine palladium 0 PubChem CID: 2734558 IUPAC-namn: palladium; tritert-butylfosfan LEDER: [Pd].CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C

Molekylformel C24H54P2Pd
PubChem CID 2734558
MDL-nummer MFCD03094580
IUPAC-namn palladium; tritert-butylfosfan
CAS 53199-31-8
InChI-nyckel MXQOYLRVSVOCQT-UHFFFAOYSA-N
LEDER [Pd].CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C
Molekylvikt (g/mol) 511.06
Synonym bis tri-tert-butylphosphine palladium 0,bis tri-t-butylphosphine palladium 0,bis tri-tert-butylphosphine palladium,bis tri-tert-butylphosphane palladium,palladium; tritert-butylphosphane,palladium, bis tris 1,1-dimethylethyl phosphine,pd p tbu 3 2,pd t-bu3p 2,bis tri-t-butylphosphine palladium,di tri-tert-butylphosphine palladium 0
7

3-(Diphenylphosphino)propylamine, 97+%

CAS: 16605-03-1 Molekylformel: C15H18NP Molekylvikt (g/mol): 243.29 MDL-nummer: MFCD00233832 InChI-nyckel: DQZWMOWSTWWMPP-UHFFFAOYSA-N Synonym: 3-diphenylphosphino-1-propylamine,3-diphenylphosphino propan-1-amine,3-aminopropyl diphenylphosphine,3-diphenylphosphino propylamine,3-diphenylphosphanyl-propylamine,1-propanamine,3-diphenylphosphino,3-aminopropyl diphenylphosphane,3-diphenylphosphanyl propan-1-amine,acmc-20aniq,3-aminopropyldiphenylphosphine PubChem CID: 280677 IUPAC-namn: 3-difenylfosfanylpropan-1-amin LEDER: NCCCP(C1=CC=CC=C1)C1=CC=CC=C1

Molekylformel C15H18NP
PubChem CID 280677
MDL-nummer MFCD00233832
IUPAC-namn 3-difenylfosfanylpropan-1-amin
CAS 16605-03-1
InChI-nyckel DQZWMOWSTWWMPP-UHFFFAOYSA-N
LEDER NCCCP(C1=CC=CC=C1)C1=CC=CC=C1
Molekylvikt (g/mol) 243.29
Synonym 3-diphenylphosphino-1-propylamine,3-diphenylphosphino propan-1-amine,3-aminopropyl diphenylphosphine,3-diphenylphosphino propylamine,3-diphenylphosphanyl-propylamine,1-propanamine,3-diphenylphosphino,3-aminopropyl diphenylphosphane,3-diphenylphosphanyl propan-1-amine,acmc-20aniq,3-aminopropyldiphenylphosphine
8

Diklorobis(di-tert-butylfenylfosfin)palladium(II), Pd 16,1 %, Thermo Scientific Chemicals

CAS: 34409-44-4 Molekylformel: C28H46Cl2P2Pd Molekylvikt (g/mol): 621.94 MDL-nummer: MFCD09953450 InChI-nyckel: DFKFLLBQLYGVIH-UHFFFAOYSA-L Synonym: dichlorobis di-tert-butylphenylphosphine palladium ii,bis di-t-butyl phenyl phosphine palladium dichloride,bis di-tert-butyl phenyl phosphane ; palladium chloride PubChem CID: 56649816 IUPAC-namn: ditert-butyl(fenyl)fosfan; diklorpalladium LEDER: Cl[Pd++]Cl.CC(C)(C)P(C1=CC=CC=C1)C(C)(C)C.CC(C)(C)P(C1=CC=CC=C1)C(C)(C)C

Molekylformel C28H46Cl2P2Pd
PubChem CID 56649816
MDL-nummer MFCD09953450
IUPAC-namn ditert-butyl(fenyl)fosfan; diklorpalladium
CAS 34409-44-4
InChI-nyckel DFKFLLBQLYGVIH-UHFFFAOYSA-L
LEDER Cl[Pd++]Cl.CC(C)(C)P(C1=CC=CC=C1)C(C)(C)C.CC(C)(C)P(C1=CC=CC=C1)C(C)(C)C
Molekylvikt (g/mol) 621.94
Synonym dichlorobis di-tert-butylphenylphosphine palladium ii,bis di-t-butyl phenyl phosphine palladium dichloride,bis di-tert-butyl phenyl phosphane ; palladium chloride
9

Dicyklohexylklorfosfin, 98+%, Thermo Scientific Chemicals

CAS: 16523-54-9 Molekylformel: C12H22ClP Molekylvikt (g/mol): 232.73 MDL-nummer: MFCD00014294 InChI-nyckel: AKJFBIZAEPTXIL-UHFFFAOYSA-N Synonym: chlorodicyclohexylphosphine,dicyclohexylchlorophosphine,dicyclohexylphosphinous chloride,dicyclohexylphosphine chloride,chlorodicyclohexyl phosphine,phosphinous chloride, dicyclohexyl,clpcy2,pcy2cl,chlorodicyclohexvlphosphine,dicyclohexylchlorophosphane PubChem CID: 2734135 LEDER: ClP(C1CCCCC1)C1CCCCC1

Molekylformel C12H22ClP
PubChem CID 2734135
MDL-nummer MFCD00014294
CAS 16523-54-9
InChI-nyckel AKJFBIZAEPTXIL-UHFFFAOYSA-N
LEDER ClP(C1CCCCC1)C1CCCCC1
Molekylvikt (g/mol) 232.73
Synonym chlorodicyclohexylphosphine,dicyclohexylchlorophosphine,dicyclohexylphosphinous chloride,dicyclohexylphosphine chloride,chlorodicyclohexyl phosphine,phosphinous chloride, dicyclohexyl,clpcy2,pcy2cl,chlorodicyclohexvlphosphine,dicyclohexylchlorophosphane
10

(R,R)-DIPAMP, 90%

CAS: 55739-58-7 Molekylformel: C28H28O2P2 Molekylvikt (g/mol): 458.48 MDL-nummer: MFCD05863546 InChI-nyckel: QKZWXPLBVCKXNQ-UHFFFAOYNA-N Synonym: r,r-dipamp,1,2-bis r-2-methoxyphenyl phenyl phosphino ethane,unii-blj831owlw,--dipamp,r,r-ethylenebis 2-methoxyphenyl phenylphosphine,r,r-1,2-bis 2-methoxyphenyl phenylphosphino ethane,blj831owlw,s,s-dipamp,1r,2r---bis 2-methoxyphenyl phenylphosphino ethane PubChem CID: 10884975 LEDER: COC1=C(C=CC=C1)P(CCP(C1=CC=CC=C1)C1=C(OC)C=CC=C1)C1=CC=CC=C1

Molekylformel C28H28O2P2
PubChem CID 10884975
MDL-nummer MFCD05863546
CAS 55739-58-7
InChI-nyckel QKZWXPLBVCKXNQ-UHFFFAOYNA-N
LEDER COC1=C(C=CC=C1)P(CCP(C1=CC=CC=C1)C1=C(OC)C=CC=C1)C1=CC=CC=C1
Molekylvikt (g/mol) 458.48
Synonym r,r-dipamp,1,2-bis r-2-methoxyphenyl phenyl phosphino ethane,unii-blj831owlw,--dipamp,r,r-ethylenebis 2-methoxyphenyl phenylphosphine,r,r-1,2-bis 2-methoxyphenyl phenylphosphino ethane,blj831owlw,s,s-dipamp,1r,2r---bis 2-methoxyphenyl phenylphosphino ethane
11

Etyldifenylfosfin, 98 %, Thermo Scientific Chemicals

CAS: 607-01-2 Molekylformel: C14H15P Molekylvikt (g/mol): 214.25 MDL-nummer: MFCD00015170 InChI-nyckel: WUOIAOOSKMHJOV-UHFFFAOYSA-N Synonym: ethyldiphenylphosphine,phosphine, ethyldiphenyl,diphenyl ethyl phosphine,diphenylphosphinoethane,diphenylphosphinoethan,ethyl diphenylphosphine,ethyl diphenyl phosphane,acmc-209mlk,ethyl diphenyl phosphine PubChem CID: 69082 IUPAC-namn: etyl(difenyl)fosfan LEDER: CCP(C1=CC=CC=C1)C1=CC=CC=C1

Molekylformel C14H15P
PubChem CID 69082
MDL-nummer MFCD00015170
IUPAC-namn etyl(difenyl)fosfan
CAS 607-01-2
InChI-nyckel WUOIAOOSKMHJOV-UHFFFAOYSA-N
LEDER CCP(C1=CC=CC=C1)C1=CC=CC=C1
Molekylvikt (g/mol) 214.25
Synonym ethyldiphenylphosphine,phosphine, ethyldiphenyl,diphenyl ethyl phosphine,diphenylphosphinoethane,diphenylphosphinoethan,ethyl diphenylphosphine,ethyl diphenyl phosphane,acmc-209mlk,ethyl diphenyl phosphine
12

Isopropyldiphenylphosphine, 99%

CAS: 6372-40-3 Molekylformel: C15H17P Molekylvikt (g/mol): 228.28 MDL-nummer: MFCD00015028 InChI-nyckel: LLZAIAIZAVMQIG-UHFFFAOYSA-N Synonym: isopropyldiphenylphosphine,phosphine, 1-methylethyl diphenyl,isopropyldiphenylphosphane,isopropyl diphenyl phosphine,acmc-209nho,isopropyl-diphenylphosphine,diphenyl propan-2-yl phosphane,i-propyldiphenylphosphine PubChem CID: 80754 IUPAC-namn: difenyl(propan-2-yl)fosfan LEDER: CC(C)P(C1=CC=CC=C1)C1=CC=CC=C1

Molekylformel C15H17P
PubChem CID 80754
MDL-nummer MFCD00015028
IUPAC-namn difenyl(propan-2-yl)fosfan
CAS 6372-40-3
InChI-nyckel LLZAIAIZAVMQIG-UHFFFAOYSA-N
LEDER CC(C)P(C1=CC=CC=C1)C1=CC=CC=C1
Molekylvikt (g/mol) 228.28
Synonym isopropyldiphenylphosphine,phosphine, 1-methylethyl diphenyl,isopropyldiphenylphosphane,isopropyl diphenyl phosphine,acmc-209nho,isopropyl-diphenylphosphine,diphenyl propan-2-yl phosphane,i-propyldiphenylphosphine
13

Cyclohexyldiphenylphosphine, 98%

CAS: 6372-42-5 Molekylformel: C18H21P Molekylvikt (g/mol): 268.34 MDL-nummer: MFCD00046360 InChI-nyckel: ZXKWUYWWVSKKQZ-UHFFFAOYSA-N Synonym: cyclohexyldiphenylphosphine,phosphine, cyclohexyldiphenyl,cyclohexyl diphenyl phosphine,diphenylcyclohexylphosphine,diphenylphosphinocyclohexane,cyclohexyl-diphenyl-phosphane,pubchem6451,acmc-1ba4g,cyclohexyl diphenyl phosphane PubChem CID: 80756 LEDER: C1CCC(CC1)P(C1=CC=CC=C1)C1=CC=CC=C1

Molekylformel C18H21P
PubChem CID 80756
MDL-nummer MFCD00046360
CAS 6372-42-5
InChI-nyckel ZXKWUYWWVSKKQZ-UHFFFAOYSA-N
LEDER C1CCC(CC1)P(C1=CC=CC=C1)C1=CC=CC=C1
Molekylvikt (g/mol) 268.34
Synonym cyclohexyldiphenylphosphine,phosphine, cyclohexyldiphenyl,cyclohexyl diphenyl phosphine,diphenylcyclohexylphosphine,diphenylphosphinocyclohexane,cyclohexyl-diphenyl-phosphane,pubchem6451,acmc-1ba4g,cyclohexyl diphenyl phosphane
14

Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II)

CAS: 15629-92-2 Molekylformel: C27H26Cl2NiP2 Molekylvikt (g/mol): 542.04 MDL-nummer: MFCD00015318 InChI-nyckel: REQVOKPBMSCTNI-UHFFFAOYSA-L Synonym: 1,3-Bis(diphenylphosphino)propane nickel(II) chloride PubChem CID: 131675641 IUPAC-namn: 3-difenylfosfanylpropyl(difenyl)fosfan;nickel;dihydroklorid LEDER: Cl[Ni++]Cl.C(CP(C1=CC=CC=C1)C1=CC=CC=C1)CP(C1=CC=CC=C1)C1=CC=CC=C1

Molekylformel C27H26Cl2NiP2
PubChem CID 131675641
MDL-nummer MFCD00015318
IUPAC-namn 3-difenylfosfanylpropyl(difenyl)fosfan;nickel;dihydroklorid
CAS 15629-92-2
InChI-nyckel REQVOKPBMSCTNI-UHFFFAOYSA-L
LEDER Cl[Ni++]Cl.C(CP(C1=CC=CC=C1)C1=CC=CC=C1)CP(C1=CC=CC=C1)C1=CC=CC=C1
Molekylvikt (g/mol) 542.04
Synonym 1,3-Bis(diphenylphosphino)propane nickel(II) chloride
15

Bis(3-aminopropyl)fenylfosfin, Thermo Scientific Chemicals

CAS: 6775-01-5 Molekylformel: C12H21N2P Molekylvikt (g/mol): 224.29 MDL-nummer: MFCD00014834 InChI-nyckel: OEHBMEXOPYWPKQ-UHFFFAOYSA-N Synonym: bis 3-aminopropyl phenylphosphine,3,3'-phenylphosphinediyl bis propan-1-amine,3-3-aminopropyl phenyl phosphanyl propan-1-amine,bis 3-aminopropyl phenyl phosphane,1-propanamine,3,3'-phenylphosphinidene bis-9ci,bis 3-aminopropyl phenylphosphine, packaged under argon in resealable chemseal bottles PubChem CID: 138827 IUPAC-namn: 3-[3-aminopropyl(fenyl)fosfanyl]propan-1-amin LEDER: NCCCP(CCCN)C1=CC=CC=C1

Molekylformel C12H21N2P
PubChem CID 138827
MDL-nummer MFCD00014834
IUPAC-namn 3-[3-aminopropyl(fenyl)fosfanyl]propan-1-amin
CAS 6775-01-5
InChI-nyckel OEHBMEXOPYWPKQ-UHFFFAOYSA-N
LEDER NCCCP(CCCN)C1=CC=CC=C1
Molekylvikt (g/mol) 224.29
Synonym bis 3-aminopropyl phenylphosphine,3,3'-phenylphosphinediyl bis propan-1-amine,3-3-aminopropyl phenyl phosphanyl propan-1-amine,bis 3-aminopropyl phenyl phosphane,1-propanamine,3,3'-phenylphosphinidene bis-9ci,bis 3-aminopropyl phenylphosphine, packaged under argon in resealable chemseal bottles